Search results for "x-ray spectroscopy"

New Regularization Method for EXAFS Analysis

2007

As an alternative to the analysis of EXAFS spectra by conventional shell fitting, the Tikhonov regularization method has been proposed. An improved algorithm that utilizes a priori information about the sample has been developed and applied to the analysis of U L3‐edge spectra of soddyite, (UO2)2SiO4⋅2H2O, and of U(VI) sorbed onto kaolinite. The partial radial distribution functions g1(UU), g2(USi), and g3(UO) of soddyite agree with crystallographic values and previous EXAFS results.

Hard X-Ray Response of Pixellated CdZnTe Detectors

2009

In recent years, the development of cadmium zinc telluride (CdZnTe) detectors for x-ray and gamma ray spectrometry has grown rapidly. The good room temperature performance and the high spatial resolution of pixellated CdZnTe detectors make them very attractive in space-borne x-ray astronomy, mainly as focal plane detectors for the new generation of hard x-ray focusing telescopes. In this work, we investigated on the spectroscopic performance of two pixellated CdZnTe detectors coupled with a custom low noise and low power readout application specific integrated circuit (ASIC). The detectors (10x10x1 and 10x10x2 mm3 single crystals) have an anode layout based on an array of 256 pixels with a …

Synthesis and thermoelectric characterisation of bismuth nanoparticles

2009

An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi(SC12H25)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispe…

Fabrication of Electrical Contacts on Pyramid-Shaped NTD-Ge Microcalorimeters Using Free-Standing Shadow Masks

2011

In our effort to fabricate arrays of germanium microcalorimeters for X-ray detection, a truncated square-based pyramid shape has been identified as a suitable geometry for the sensors. It allows to obtain a uniform current spreading across each sensor, and represents a good compromise between having a large support area for the radiation absorber and for maintaining an overall small bolometer volume. This three-dimensional geometry, however, does not allow to create the electrical contacts for the sensors using a regular photoresist-based lift-off metallization process. In this paper we show how to deposit metal contacts on the lateral faces of the pyramidal sensors by metal evaporation thr…

Microwave-induced electromigration in multicomponent metallic alloys

2010

The crystallization of amorphous FeCoCuZrAlSiB alloy ribbons during microwave heating was investigated in situ using time-resolved X-ray powder diffraction. The formation of the nanocrystalline α-(Fe,Co)(SiAl) phase during the primary crystallization stage is followed by the crystallization of the residual glassy matrix. Scanning electron microscopy analysis after microwave exposure reveals the formation of nanosized hillocks evenly distributed over the ribbon surfaces. Local chemical composition analysis by energy-dispersive spectroscopy shows that the surface clusters are enriched in Cu and Al. The occurrence of this typical electromigration effect imposes a strong restriction on the dura…

Hard-X-ray-induced excited-spin-state trapping.

2007

Spectral broadening by incomplete thermalization of the energy in X-ray microcalorimeters with superconducting absorber and NTD-Ge thermal sensor

2004

Abstract We present a model of the response of a cryogenic microcalorimeter with superconducting absorber and phonon sensitive thermal sensor to the absorption of X-ray photons. The model is based on the main microscopic processes responsible for the thermalization of the deposited energy. We use a system of rate equations to describe the energy downconversion in the superconductor and transport to the thermal sensor. The model is a tool to investigate the thermalization efficiency with respect to the device characteristics (i.e. absorber material, geometry), in order to optimize the performances of these detectors. As a first case study, we report results of simulations for a microcalorime…

Characterization of Iranian Moarraque glazes by light microscopy, SEM-EDX and voltammetry of microparticles

2008

Abstract Glazed ceramics have been traditionally used in Iran for decorating mosques and some civil historical buildings. In particular, Moarraque glazes have been extensively used in the indoor and outdoor decoration of mosques in Iran since the middle 14th century. The pieces have a complex elaboration based on a main glazed piece corresponding to the skeleton structure of the Shah Abbasi flower, which contains a number of holes, where are placed, mosaic-like, smaller glazed pieces forming a compact and single tile. The present work describes the analytical study performed on the glazes of several pieces of Moarraque tiles from the Ali Ebn Abi Taleb Mosque (Esfahan, Iran), which date back…

X-ray Spectroscopy of (Ba,Sr,La)(Fe,Zn,Y)O3-δIdentifies Structural and Electronic Features Favoring Proton Uptake

2020

Mixed protonic–electronic conducting oxides are key functional materials for protonic ceramic fuel cells. Here, (Ba,Sr,La)(Fe,Zn,Y)O3−δ perovskites are comprehensively investigated by X-ray spectroscopy (in oxidized and reduced states). Extended X-ray absorption fine structure shows that Zn,Y doping strongly increases the tendency for Fe–O–Fe buckling. X-ray absorption near-edge spectroscopy at the Fe K-edge and X-ray Raman scattering at the O K edge demonstrate that both iron and oxygen states are involved when the samples are oxidized, and for the Zn,Y doped materials, the hole transfer from iron to oxygen is less pronounced. This can be correlated with the observation that these material…

Performance of a digital CdTe X-ray spectrometer in low and high counting rate environment

2010

Abstract The high performances of CdTe detectors for X-ray and gamma ray spectroscopy are already well known. Among the traditional semiconductor spectrometers, CdTe detectors show high detection efficiency and good room temperature performance and are well suited for the development of compact detection systems. In this work, we investigated the performance of a CdTe detector coupled with a custom digital pulse processing (DPP) system for X-ray spectroscopy. The DPP method, implemented on a PC platform, performs a pile-up inspection and a pulse height analysis of the preamplifier output pulses, digitized by a 14-bit, 100 MHz ADC. The spectroscopic results point out the excellent performanc…